Quebec-selected skilled workers
Under the Canada-Quebec Accord on Immigration, Quebec establishes its own immigration requirements and selects immigrants who will adapt well to living in Quebec.
If you want to go to Quebec as a skilled worker, you must first follow a separate selection process before your application is finalised by Citizenship and Immigration Canada. If you speak French, you should know that there are plenty of French-speaking communities outside Quebec that are also excited about welcoming you.
References:Citizenship and Immigration Canada / Immigration and Refugee Board